کالای فیزیکی
اگزالیل کلرید مرک Oxalyl chloride 807066
کالای فیزیکی

اگزالیل کلرید مرک Oxalyl chloride 807066

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اگزالیل کلرید مرک

Oxalyl chloride

807066

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Chemical Synthesis

807066

Oxalyl chloride for synthesis

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8.07066

Sigma-Aldrich

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for synthesis

Synonym(s):

Oxalyl chloride, Oxalic acid dichloride

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25 ML

€55.60

100 ML

€100.00


About This Item

Empirical Formula (Hill Notation):

C2Cl2O2

CAS Number:

79-37-8

Molecular Weight:

126.93

MDL number:

MFCD00000704

UNSPSC Code:

12352106

EC Index Number:

201-200-2

NACRES:

NA.22


8070660025

€55.60


Availability

Estimated to ship onFebruary 07, 2025


To order products, please contact your local dealer.

فروش مواد شیمیایی

vapor pressure

200 hPa ( 20 °C)

Quality Level

200

form

liquid

bp

63-64 °C/1013 hPa

mp

-12 °C

transition temp

flash point >100 °C

density

1.48 g/cm3 at 20 °C

storage temp.

2-30°C

InChI

1S/C2Cl2O2/c3-1(5)2(4)6

InChI key

CTSLXHKWHWQRSH-UHFFFAOYSA-N

  • Mild deprotection of the N-tert-butyloxycarbonyl (N-Boc) group using oxalyl chloride: This study explores the mild deprotection capabilities of oxalyl chloride on N-Boc substrates, offering a potential method for sensitive chemical syntheses (N George, S Ofori, S Parkin, SG Awuah, 2020).

  • Nickel-Catalyzed Highly Selective Reductive Carbonylation Using Oxalyl Chloride as the Carbonyl Source: Demonstrates the use of oxalyl chloride as an effective carbonyl source in nickel-catalyzed reductive carbonylation, highlighting its utility in organic synthesis (J Wang, Y Yin, X He, QL Duan, R Bai, HW Shi, 2023).

  • A novel and highly efficient esterification process using triphenylphosphine oxide with oxalyl chloride: Introduces a novel esterification process utilizing oxalyl chloride and triphenylphosphine oxide, which improves reaction efficiency and product yield in organic chemistry (M Jia, L Jiang, F Niu, Y Zhang, 2018).

  • Dimethyl sulfoxide/oxalyl chloride: A useful reagent for sulfenyletherification: Discusses the use of a dimethyl sulfoxide/oxalyl chloride mixture in sulfenyletherification reactions, providing insights into advanced synthesis techniques for sulfur-containing compounds (Y Gao, S Cheng, T Zhang, R Ding, Y Liu, 2018).

Analysis Note

Assay (argentometric): ≥ 98.0 %
Identity (IR): passes test
A slight precipitate of oxalic acid is normal and does not affect the specified quality of the product.

Safety Information

Pictograms

FlameCorrosionSkull and crossbones

GHS02,GHS05,GHS06

Signal Word

Danger

Hazard Statements

H260 - H301 + H331 - H314

Precautionary Statements

P223 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B - Water-react 1

Supplementary Hazards

EUH014 - EUH029 - EUH071

Storage Class Code

4.3 - Hazardous materials, which set free flammable gases upon contact with water

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

807066 Sigma-AldrichOxalyl chloride

Oxalyl chloride for synthesis. CAS 79-37-8, EC Number 201-200-2, chemical formula ClCOCOCl.

Oxalyl chloride MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: Oxalic acid dichloride

CAS #: 79-37-8 EC Number: 201-200-2 Molar Mass: 126.92 g/mol Chemical Formula: ClCOCOCl Hill Formula: C₂Cl₂O₂

807066

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Overview

Key Spec Table

CAS #

EC Number

Hill Formula

Chemical Formula

Molar Mass

79-37-8

201-200-2

C₂Cl₂O₂

ClCOCOCl

126.92 g/mol

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Availability

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Price

Quantity

8070660025

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25 ml

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8070660100

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100 ml

EUR 98.10

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Description

Catalogue Number

807066

Synonyms

Oxalic acid dichloride

Description

Oxalyl chloride

Product Information

CAS number

79-37-8

EC number

201-200-2

Hill Formula

C₂Cl₂O₂

Chemical formula

ClCOCOCl

Molar Mass

126.92 g/mol

HS Code

2917 11 10

Structure formula Image

Structure formula Image

Quality Level

MQ200

Applications

Application

Oxalyl chloride for synthesis. CAS 79-37-8, EC Number 201-200-2, chemical formula ClCOCOCl.

Physicochemical Information

Boiling point

63 - 64 °C (1013 hPa)

Density

1.455 g/cm3 (20 °C)

Melting Point

-12 °C

Vapor pressure

199.98 hPa (20 °C)

Safety Information according to GHS

Hazard Pictogram(s)

Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)

Hazard Statement(s)

H260: In contact with water releases flammable gases which may ignite spontaneously.
H301 + H331: Toxic if swallowed or if inhaled.
H314: Causes severe skin burns and eye damage.
EUH014: Reacts violently with water.
EUH029: Contact with water liberates toxic gas.
EUH071: Corrosive to the respiratory tract.

Precautionary Statement(s)

P223: Do not allow contact with water.
P231 + P232: Handle and store contents under inert gas. Protect from moisture.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P402 + P404: Store in a dry place. Store in a closed container.

Signal Word

Danger

RTECS

KI2950000

Storage class

4.3 Hazardous materials, which set free flammable gases upon contact with water

WGK

WGK 2 obviously hazardous to water

Disposal

11
Organic acid halides, anhydrides and isocyanates can be added dropwise to an excess of methanol (Cat. No. 822283) to convert them into the corresponding methyl esters or methyl carbamates. If necessary, neutralize with sodium hydroxide solution (Cat. No. 105587). Fill into container A.

Safety Information

Categories of danger

toxic, corrosive

Storage and Shipping Information

Storage

Store below +30°C.

Transport Information

Declaration (railroad and road) ADR, RID

UN 3129 , 4.3 (8), I

Declaration (transport by air) IATA-DGR

UN 3129 , 4.3 (8), I

Declaration (transport by sea) IMDG-Code

UN 3129 , 4.3 (8), I, Segregation Group: 1 (Acids)

Specifications

Assay (argentometric)

≥ 98.0 %

Identity (IR)

passes test

Color (visual)

colorless to pale yellow

Appearance of substance (visual)

clear

A slight precipitate of oxalic acid is normal and does not affect the specified quality of the product.

Global Trade Item Number

Catalogue Number

GTIN

8070660025

04022536393674

8070660100

04022536393681

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